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Synthesis and Applications of New Spin Crossover Compounds

The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials—promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscle...

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Guardat en:
Autor principal: Kitazawa, Takafumi
Format: Online
Idioma:anglès
Publicat: MDPI - Multidisciplinary Digital Publishing Institute 2021
Matèries:
Q1-390
QC1-999
n/a
hexadentate ligand
X-ray diffraction
structural disorder
lattice energy
2-bis(4-pyridyl)ethane
thermal hysteresis
optical conductivity spectrum
spin-state crossover
solvate
single crystal
spin-crossover transition
spin-crossover
cobalt oxide
amorphous
metal dithiolene complexes
qsal ligand
impurity effect
3-triazole
intermolecular interactions
spin crossover
hydrogen bonding
1
2
optical microscopy
supramolecular coordination polymer
paramagnetic ligand
magnetic susceptibility
high spin
[Fe(III)(3-OMesal2-trien)]+
aminoxyl
cobalt(II) ion
mosaicity
Fe(III) coordination complexes
nitroxides
C–H···? interactions
Fe(II)
dithiooxalato ligand
dinuclear triple helicate
coordination polymers
magnetization
spiral structure
magnetostructural correlations
charge-transfer phase transition
structure phase transition
magnetic properties
spin polaron
substitution of 3d transition metal ion
iron(II) complexes
X-ray absorption spectroscopy
coordination complexes
crystal engineering
fatigability
soft X-ray induced excited spin state trapping
spin transition
dipyridyl-N-alkylamine ligands
coordination polymer
iron (II)
iron mixed-valence complex
chiral propeller structure
spin cross-over (SCO)
EPR spectroscopy
Cu(II) complexes
solvent effects
ferromagnetism
SQUID
LIESST effect
low spin (LS)
57Fe Mössbauer spectroscopy
dielectric response
iron(II)
hetero metal complex
atropisomerism
switch
Schiff base
counter-anion
DFT calculation
Fe(III) complex
Fe(II) complex
high spin (HS)
reaction diffusion
thermochromism
supramolecular isomerism
phase transition
magnetic transition
mononuclear
[Au(dmit)2]?
UV-Vis spectroscopy
phase transitions
?-? interactions
[Au(dddt)2]?
crystal structure
linear pentadentate ligand
ion-pair crystals
bic Book Industry Communication::G Reference, information & interdisciplinary subjects::GP Research & information: general
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